Search results for "AUSTENITIC STAINLESS-STEEL"

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Effect of temperature on the passive state of Alloy 31 in a LiBr solution: Passivation and Mott-Schottky analysis

2015

The passive behaviour of Alloy 31, a highly-alloyed austenitic stainless steel (UNS N08031), has been investigated in a LiBr heavy brine (700 g/l) at different temperatures using potentiostatic polarisation and Mott-Schottky analysis. Cation vacancies have been found to be the dominant defect in the passive films formed on Alloy 31. An increase in temperature enhanced the generation of cation vacancies at the film/solution interface and raised the steady-state passive current density. The density of defects within the passive film also increased significantly with temperature, making the film more conductive and less protective against localised attacks.

CARBON-STEELAUSTENITIC STAINLESS-STEELBORATE BUFFER SOLUTIONOXIDE-FILMSINGENIERIA QUIMICAElectroquímicaPOINT-DEFECT MODELELECTRONIC-STRUCTUREREPASSIVATION KINETICSELECTROCHEMICAL-IMPEDANCE SPECTROSCOPYPOTENTIAL DISTRIBUTIONACTIVITY-COEFFICIENTSAcer Corrosió
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Multiscale modeling of polycrystalline materials: A boundary element approach to material degradation and fracture

2015

Abstract In this work, a two-scale approach to degradation and failure in polycrystalline materials is proposed. The formulation involves the engineering component level (macro-scale) and the material grain level (micro-scale). The macro-continuum is modeled using a three-dimensional boundary element formulation in which the presence of damage is formulated through an initial stress approach to account for the local softening in the neighborhood of points experiencing degradation at the micro-scale. The microscopic degradation is explicitly modeled by associating Representative Volume Elements (RVEs) to relevant points of the macro continuum, for representing the polycrystalline microstruct…

TechnologyComputational MechanicsPolycrystalline materialsGeneral Physics and AstronomyMultiscale formulationNANOMECHANICSDIFFRACTION09 EngineeringEngineeringPolycrystalline materialComputational mechanicsPeriodic boundary conditionsFAILUREPLASTICITYComputational MechanicApplied MathematicsAUSTENITIC STAINLESS-STEELComputer Science Applications1707 Computer Vision and Pattern RecognitionMechanicsStructural engineeringREPRESENTATIVE VOLUME ELEMENTMicrostructureStrength of materialsMultiscale modelingComputer Science ApplicationsMechanics of MaterialsMultiscale formulationsPhysical SciencesSIMULATIONMicromechanicsSTRESS-CORROSION CRACKINGMathematics Interdisciplinary ApplicationsMaterials scienceHOMOGENIZATIONEngineering MultidisciplinaryMechanicsPhysics and Astronomy (all)Boundary element methodMechanics of MaterialBoundary element methodFORMULATIONMicromechanicSHORT FATIGUE-CRACK01 Mathematical SciencesScience & Technologybusiness.industryMechanical EngineeringMicromechanicsDamage and fractureMICROSTRUCTUREbusinessVoronoi diagramMathematics
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